Create New Distribution Group:
- In the Microsoft 365 admin center, navigate to Groups and Add a Group.

- On the Add group window, under Choose a group type select Distribution. Click Next.

- On the Set up the basics page, enter a Name, and Description if you choose. Click Next.

- On the Edit settings page, check the box to Allow people outside of my organization to send email to this distribution group. Click Next.

- On the Review and finish adding group, review the information and click Create group.

- Once your New group (is) created, click Close.

Create Contact for External Users:
- In the Microsoft 365 admin center, navigate to Contacts. Then Add a contact.

- On the Add a contact window, enter the required information and click Add.

- Close the Add a contact window.

- Verify that your contact was created.

Add Contact to Group
- In the Microsoft 365 admin center, navigate to Groups. Double-click to open the group.

- In the Group details window, on the Members tab, click View all and manage members.

- Click Add members.

- In the Add members list, select the Contacts you created. Click Save.

- Once Group members were added, click Close.

- Click Close.

- Click Close once again.

- Your Distribution Group with external Contacts has been created and ready for use.

https://www.cloudservus.com/how-to-add-external-users-to-a-distribution-group/